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New ultra-thin electronic films offer greater capabilities

May 14, 2012 | Paul Buckley | 222904589
New ultra-thin electronic films offer greater capabilities As the result of a French-American collaboration spearheaded by the Centre de Recherches sur les Macromolécules Végétales, a new combination of polymers associating sugars with oil-based macromolecules is helping to design ultra-thin films capable of self-organization with a 5-nm resolution.
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The new research will open up new horizons for increasing the capacity of hard discs and the speed of microprocessors. The new class of thin films based on hybrid copolymers could give rise to numerous applications in flexible electronics, in areas as diverse as nanolithography, biosensors and photovoltaic cells.

Before new generations of microprocessors can be devised, an evolution in lithography, the technique used for printing electronic circuits, is indispensable. Until now, the thin films used in electronic circuits have been designed from synthetic polymers exclusively derived from petroleum. The thin films have limitations: their minimum structural resolution is around 20 nm and cannot be reduced further by combining petroleum-derived polymers. This limit has been one of the main obstacles to the development of new generations of very-high-resolution flexible electronic devices.

Why was there such a limit? Because of the low incompatibility between the two blocks of polymers, both derived from oil. For that reason, the team headed by Redouane Borsali, CNRS senior researcher at the Centre de Recherches sur les Macromolcules Vgtales (CERMAV), came up with a hybrid material: this new class of thin films combines sugar-based and petroleum-derived (silicon containing polystyrene) polymers with widely different physical/chemical characteristics.

The copolymer, formed of highly incompatible elementary building blocks, is similar to an oil bubble attached to a small water bubble. The researchers have shown that this type of structure is capable of organizing itself into sugar cylinders within a petroleum-based polymer lattice, each structure having a size of 5 nanometers, i.e. much smaller than the resolution of 'old' copolymers, exclusively composed of petroleum derivatives. In addition, this new generation of material is made from an abundant, renewable and biodegradable resource: sugar.
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